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Exam 10: Alcohols

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Question 51

Multiple Choice

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What is the IUPAC name of the following compound?

A) (E) -5-methyl-2-hexen-5-ol
B) (Z) -5-methyl-2-hexen-5-ol
C) (E) -2-methyl-4-hexen-2-ol
D) (Z) -2-methyl-4-hexen-2-ol

E) A) and D)
F) A) and C)

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Question 52

Multiple Choice

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What is the IUPAC name of the following compound?

A) 3-methyl-1-penten-4-ol
B) 3-methyl-4-penten-2-ol
C) 1,2-dimethyl-2-propan-1-ol
D) 2,3-dimethyl-1-propan-3-ol

E) None of the above
F) B) and C)

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Question 53

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What is the major organic product obtained from the following reaction?

What is the major organic product obtained from the following reaction?

Which of the following alcohols undergoes the most rapid dehydration upon treatment with H₂SO₄ to give an alkene?

What type of reactive intermediate is formed in the reaction of tert-butyl alcohol with H₂SO₄ to give methylpropene?

Consider the following structures. Structure(s)____could be used to produce an aldehyde by reaction with PCC. Enter the number of the appropriate structure. If more than one structure is correct, enter the appropriate numbers separated by commas.

To answer the following question, consider the reaction below: -Provide the complete IUPAC name for the starting material in this reaction.

What is the best choice of reagent to achieve the following transformation?

What is the major organic product obtained from the following reaction?

What is the major organic product obtained from the following reaction?

What is the major organic product obtained from the following reaction?

Which of the following best describes the reaction of sodium metal with methanol to give hydrogen and sodium methoxide?

(CH₃)₃CO^- Na⁺ would be formed by the reaction of sodium metal and 1-butanol.

What is the major organic product obtained from the following reaction?

Consider following structures. Only structure III represents a secondary alcohol.

_______Oxidation of a secondary alcohol to a ketone.

What is the IUPAC name of the following compound (shown as a Fischer projection)?