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Which of the following combinations of peaks appears in the 1H NMR spectrum of 2,3-dimethylbutane?


A) two doublets
B) a doublet and a septet
C) a singlet and two doublets
D) a doublet and an octet

E) C) and D)
F) A) and B)

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A

How many signals appear in the proton-decoupled 13C NMR spectrum of the following compound? How many signals appear in the proton-decoupled <sup>13</sup>C NMR spectrum of the following compound?   A)  7 B)  8 C)  9 D)  11


A) 7
B) 8
C) 9
D) 11

E) A) and B)
F) All of the above

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Which of the following compounds gives a 1H NMR spectrum consisting of only a singlet, triplet and quintet?


A) CH3OCH2CH2CH2CH2OH
B) CH3OCH2CH2OCH2CH3
C) CH3OCH2CH2CH2OCH3
D) CH3OCH2CH(CH3) OCH3

E) A) and C)
F) None of the above

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How many signals appear in proton-decoupled 13C NMR spectrum of 3,4-dimethylhexane?


A) 3
B) 4
C) 5
D) 6

E) All of the above
F) C) and D)

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What is the hydrogen deficiency index for a compound with a molecular formula of C6H11N?


A) 1
B) 2
C) 3
D) 4

E) None of the above
F) C) and D)

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B

Which of the following compounds have homotopic protons? 1.propane 2.butane 3.2-methylpropane


A) only 1
B) only 2
C) only 1 and 2
D) 1, 2 and 3

E) B) and C)
F) A) and B)

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Identify the compound (C8H10) that gives the following 1H NMR spectrum. Identify the compound (C<sub>8</sub>H<sub>10</sub>) that gives the following <sup>1</sup>H NMR spectrum.

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p-xylene (...

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Which of the protons in the following molecule appear furthest downfield in the 1H NMR spectrum? Which of the protons in the following molecule appear furthest downfield in the <sup>1</sup>H NMR spectrum?   A)  i B)  ii C)  iii D)  iv


A) i
B) ii
C) iii
D) iv

E) B) and C)
F) A) and B)

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What is the hydrogen deficiency index for a compound with a molecular formula of C10H16O2?


A) 1
B) 2
C) 3
D) 4

E) None of the above
F) B) and C)

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Which of the following is not true regarding 1H NMR spectroscopy?


A) a "downfield" peak appears at a lower value of d
B) on a 300 MHz instrument, a proton that adsorbs irradiation at a frequency 900 Hz higher than the adsorption of TMS appears at d 3 ppm.
C) d for a particular proton is independent of the magnetic field strength of the instrument used.
D) "deshielding" leads to peaks at higher values of d

E) B) and C)
F) A) and B)

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How many signals appear in the proton-decoupled 13C NMR spectrum of 1,3-dibromobenzene?


A) 1
B) 2
C) 3
D) 4

E) All of the above
F) None of the above

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What is the relative area of the six peaks in a sexet in an 1H NMR spectrum?


A) 1:2:3:3:2:1
B) 1:3:6:6:3:1
C) 1:5:10:10:5:1
D) 1:6:15:15:6:1

E) B) and C)
F) A) and D)

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Which C4H9Br compound gives a doublet at approximately 3.3 ppm in the 1H NMR spectrum? Which C<sub>4</sub>H<sub>9</sub>Br compound gives a doublet at approximately 3.3 ppm in the <sup>1</sup>H NMR spectrum?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and C)
F) All of the above

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How many signals appear in the proton-decoupled 13C NMR spectrum of 1,2-dibromobenzene?


A) 1
B) 2
C) 3
D) 4

E) C) and D)
F) A) and B)

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What is the splitting of the signal in the 1H NMR spectrum for the methyl protons of propane?


A) singlet
B) doublet
C) triplet
D) quartet

E) All of the above
F) A) and C)

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Which of the protons in the following molecule appear at the highest d-value in the 1H NMR spectrum? Which of the protons in the following molecule appear at the highest d-value in the <sup>1</sup>H NMR spectrum?   A)  i B)  ii C)  iii D)  iv


A) i
B) ii
C) iii
D) iv

E) All of the above
F) A) and C)

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Which of the following compounds gives a 1H NMR spectrum consisting of two singlets and a 13C NMR consisting of consisting of three signals? Which of the following compounds gives a <sup>1</sup>H NMR spectrum consisting of two singlets and a <sup>13</sup>C NMR consisting of consisting of three signals?   A)  only i B)  only iii C)  only ii and iii D)  only ii, iii and iv


A) only i
B) only iii
C) only ii and iii
D) only ii, iii and iv

E) B) and D)
F) A) and C)

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Which C4H9Br compound(s) gives a 13C NMR spectrum consisting of two signals? Which C<sub>4</sub>H<sub>9</sub>Br compound(s)  gives a <sup>13</sup>C NMR spectrum consisting of two signals?   A)  only 1 B)  only 2 C)  only 2 and 3 D)  1, 2, 3 and 4


A) only 1
B) only 2
C) only 2 and 3
D) 1, 2, 3 and 4

E) All of the above
F) B) and D)

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Which C9H10O compound gives the following 1H NMR spectrum? Which C<sub>9</sub>H<sub>10</sub>O compound gives the following <sup>1</sup>H NMR spectrum?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and D)
F) A) and C)

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A

How many sets of equivalent protons are there in 3-methylhexane?


A) 2
B) 3
C) 6
D) 7

E) C) and D)
F) B) and D)

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