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Which of the 3 structures shown below has the shortest bond length? Justify your answer. ​ Which of the 3 structures shown below has the shortest bond length? Justify your answer. ​

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Structure 1 has the shortest bond length...

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Which of the following best represents an sp2 hybridized atomic orbital of carbon which overlaps with the 1s atomic orbital of hydrogen to form a C−H σ bonding molecular orbital in ethene, H2C=CH2 Which of the following best represents an sp<sup>2</sup> hybridized atomic orbital of carbon which overlaps with the 1s atomic orbital of hydrogen to form a C−H σ bonding molecular orbital in ethene, H<sub>2</sub>C=CH<sub>2</sub><sub> </sub>   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) B) and C)
F) A) and D)

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Which of the following species possesses a formal charge?


A) CCl4
B) SiCl4
C) AlCl4
D) PCl3

E) None of the above
F) B) and C)

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Consider the structure of urea given below. Consider the structure of urea given below.   To complete the Lewis structure, six nonbonding electrons should be added, two to each of the nitrogen atoms and two to the oxygen atom. To complete the Lewis structure, six nonbonding electrons should be added, two to each of the nitrogen atoms and two to the oxygen atom.

A) True
B) False

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How many electrons are there in the valence shell of the carbon atom of the methyl anion, CH3−?


A) 2
B) 4
C) 6
D) 8

E) A) and D)
F) B) and C)

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Which of the following statements is not true about the acetate anion, CH3CO2−?


A) The oxygen atoms bear the same amount of charge
B) The two carbon-oxygen bonds are the same length
C) The carbon atom bears the negative charge
D) It is basic

E) A) and D)
F) B) and C)

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Which of the following statements is not true?


A) The sp3C−H bond of an alkane is weaker than the spC−H bond of an alkyne.
B) The carbon-carbon triple bond of an alkyne is shorter than the carbon-carbon bond of alkenes.
C) The carbon-carbon triple bond of an alkene is exactly three times as strong as a carbon-carbon single bond of an alkane.
D) The sp3C−H bond of an alkane is longer than the spC−H bond of an alkyne.

E) B) and D)
F) A) and D)

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The following two structural formulas represent isomers. CH3CH2CH2\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \quad\quad\quad\quad | \quad\quad\quadCH2CH3\mathrm{CH}_{2} \mathrm{CH}_{3} CH3CH2CHCH3\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CHCH}_{3} \quad\quad\quad\quad | \quad\quad\quadCH2CH3\mathrm{CH}_{2} \mathrm{CH}_{3}

A) True
B) False

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The following molecule is classified as a __________amine. CH3NHCH3\mathrm { CH } _ { 3 } - \mathrm { NH } - \mathrm { CH } _ { 3 }

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Which of the following molecules has a molecular dipole moment? Which of the following molecules has a molecular dipole moment?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) B) and D)
F) A) and D)

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Which of the following molecules has a molecular dipole moment? Which of the following molecules has a molecular dipole moment?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and B)
F) B) and C)

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Which of the following bonds is the most polar?


A) O−H
B) C−H
C) C−C
D) H−H

E) A) and C)
F) All of the above

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What is the approximate C−C−C bond angle in propyne, HC≡CCH3?


A) 90°
B) 109°
C) 120°
D) 180°

E) A) and D)
F) C) and D)

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In drawing the Lewis structure for an organic compound, the carbon atoms should always be shown with eight total electrons.

A) True
B) False

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Which of the following bonds has the smallest dipole moment?


A) C−N
B) C−O
C) C−F
D) O−H

E) A) and B)
F) A) and C)

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What is the ground-state electronic configuration of a fluorine atom (fluorine: atomic number 9) ?


A) 1s12s12p7
B) 1s22s22p5
C) 1s22s22p6
D) 1s02s22p7

E) A) and C)
F) C) and D)

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What is the molecular formula of Ritalin, shown below? What is the molecular formula of Ritalin, shown below?

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Which of the following is a tertiary alcohol?


A) CH3CH2OCH3
B) (CH3) 3COH
C) (CH3) 2CHOH
D) CH3CH2CH2OH

E) C) and D)
F) B) and C)

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Which of the following bonds is a polar covalent bond?


A) Na−Cl
B) C−Cl
C) C−H
D) Cl−Cl

E) A) and B)
F) None of the above

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Fill the appropriate electronic configuration in the blank. ​ K (1s22s22p63s23p64s1) + Cl (1s22s22p63s23p5) → K+ _____ + Cl- (1s22s22p63s23p6)


A) (1s22s22p63s23p64s2)
B) (1s22s22p63s23p65s1)
C) (1s22s22p63s23p6)
D) (1s22s22p63s23p64s1)

E) B) and D)
F) A) and D)

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