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What is the condensed formula of the compound below? What is the condensed formula of the compound below?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) B) and D)
F) B) and C)

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Which of the following is the appropriate conversion of (CH3) 2CHOCH2CH2CH2OH to a skeletal structure? Which of the following is the appropriate conversion of (CH<sub>3</sub>) <sub>2</sub>CHOCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>OH to a skeletal structure?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) A) and B)
F) All of the above

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Which is more important in each pair of contributing resonance structures? Which is more important in each pair of contributing resonance structures?   A) II,IV,V B) II,III,V C) II,III,VI D) I,IV,V


A) II,IV,V
B) II,III,V
C) II,III,VI
D) I,IV,V

E) A) and B)
F) All of the above

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What is the molecular geometry around the carbon atom in CH4?


A) Tetrahedral
B) Trigonal Planar
C) Trigonal Pyramidal
D) Linear

E) A) and D)
F) B) and C)

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What is the hybridization of the carbon atom in the methyl cation,(CH3+) ?


A) sp3
B) sp2
C) sp
D) p

E) A) and D)
F) A) and C)

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Which of the following molecules has nonpolar covalent bonds?


A) HCl
B) N2
C) CHCl3
D) NO

E) B) and C)
F) B) and D)

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Rank the following atoms in order of increasing electronegativity,putting the least electronegative first. Rank the following atoms in order of increasing electronegativity,putting the least electronegative first.   A) I < II < III < IV B) I < IV < II < III C) III < II < IV < I D) I < II < IV < III


A) I < II < III < IV
B) I < IV < II < III
C) III < II < IV < I
D) I < II < IV < III

E) A) and B)
F) A) and C)

Correct Answer

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Which of the following covalent bonds has the largest dipole moment?


A) C-H
B) C-C
C) C-O
D) H-F

E) A) and C)
F) B) and C)

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What is the ground-state electronic configuration of a chlorine anion (Cl-) ?


A) 1s2,2s2,2p6
B) 1s2,2s2,2p6,3s2,3p6
C) 1s2,2s2,2p6,3s2,3p5
D) 1s2,2s2,2p6,3s2,3p4

E) None of the above
F) All of the above

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What is the formal charge of the carbon in carbon dioxide (CO2) when drawn with two double bonds?


A) +1
B) 0
C) -1
D) -2

E) A) and C)
F) A) and B)

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B

Which of the following statements correctly describes the typical number of bonds for carbon,nitrogen,and oxygen in most neutral organic molecules?


A) Carbon forms 4 covalent bonds,nitrogen forms 2 covalent bonds,and oxygen forms 3 covalent bonds.
B) Carbon forms 4 covalent bonds,nitrogen forms 3 covalent bonds,and oxygen forms 2 covalent bonds.
C) Carbon forms 4 covalent bonds,nitrogen forms 5 covalent bonds,and oxygen forms 2 covalent bonds.
D) Carbon forms 4 covalent bonds,nitrogen forms 5 covalent bonds,and oxygen forms 4 covalent bonds.

E) A) and C)
F) None of the above

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Which is the correct Lewis structure for acetic acid (CH3CO2H) ? Which is the correct Lewis structure for acetic acid (CH<sub>3</sub>CO<sub>2</sub>H) ?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) B) and C)
F) All of the above

Correct Answer

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Which of the following statements about resonance structures is true?


A) Resonance structures have the same placement of electrons but different arrangement of atoms.
B) Resonance structures have the same placement of atoms but different arrangement of electrons.
C) Resonance structures have the same placement of atoms and the same arrangement of electrons.
D) Resonance structures have different placement of atoms and different arrangement of electrons.

E) All of the above
F) None of the above

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Consider compounds which contain both a heteroatom and a double bond.For which compound is no additional Lewis structure possible? Consider compounds which contain both a heteroatom and a double bond.For which compound is no additional Lewis structure possible?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) B) and D)
F) B) and C)

Correct Answer

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Which of the following statements about electronegativity and the periodic table is true?


A) Electronegativity decreases across a row of the periodic table.
B) Electronegativity increases down a column of the periodic table.
C) Electronegativity increases across a row of the periodic table.
D) Electronegativity does not change down a column of the periodic table.

E) All of the above
F) B) and C)

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C

Which of the following molecules does not have a net dipole moment of zero?


A) CCl4
B) BF3
C) CO2
D) NH3

E) None of the above
F) All of the above

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Which is not an acceptable Lewis structure for the anion CH2NCO-? Which is not an acceptable Lewis structure for the anion CH<sub>2</sub>NCO<sup>-</sup>?   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) C) and D)
F) B) and C)

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Convert the following skeletal structure to a condensed structure. Convert the following skeletal structure to a condensed structure.   A) I B) II C) III D) IV


A) I
B) II
C) III
D) IV

E) B) and D)
F) None of the above

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A

Which of the following statements about constitutional isomers is true?


A) Constitutional isomers are different molecules having the different molecular formula.
B) Constitutional isomers are different molecules having the same molecular formula.
C) Constitutional isomers are same molecules having the different molecular formula.
D) Constitutional isomers are same molecules having the same molecular formula.

E) A) and B)
F) A) and C)

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How many constitutional isomers are there for a molecule having the molecular formula C2H4Cl2?


A) 1
B) 2
C) 3
D) 4

E) B) and D)
F) B) and C)

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